Soil is a mixture of inorganic and organic solids, air and water. Soil is key to sustaining life—affecting air and water quality, the growth of plants and crops, and the health of the entire planet. Please try again. 40 step-by-step projects, over 500 color photos, shop setup, essential tools and materials, and more! . The text covers chemical processes that occur in soils, including: distribution and species of nutrients and contaminants in soils; … Dr. George A. O’Connor is a Professor in the Soil and Water Science Department at the University of Florida in Gainesville. Meanwhile, advances in soil chemistry, soil physics, soil mineralogy, and soil biology, as well as in the basic sciences that underlie them, have added new tools and new dimensions to the study of soil formation. Download Product Flyer is to download PDF in new tab. Since then concerns have grown about environmental pollution, organic and inorganic soil contamination and potential ecological health and environmental health risks. Pages: 133. 1 mole = Avogadro’s number (6.023 x 1023) entities. This is a dummy description. . Vine- gar, containing acetic acid, is a substance that is acid. Definition Colloid: A particle, either mineral or organic, with a diameter of 0.1 to 0.001 µm. The fourth edition of Soil Chemistry has been revised and updated throughout and provides a basic description of important research and fundamental knowledge in the field. Very useful book for basic soil chemistry. 1.2.1 Soil chemical and biological interfaces 6, 1.2.3 Soil interaction with the hydrosphere 10, 1.2.4 Interaction of soil and the atmosphere 12, 1.3.1 Flow of chemical energy in soils 17, 1.3.3 Chemical reaction types in soils 18, 1.5 Soil chemical influences on food production 22, 1.6.1 Soil chemistry and environmental toxicology 24, 2 Properties of Elements and Molecules 29, 2.5 The nature of water and hydration of ions 36, 3 Characteristics of Chemicals in Soils 41, 3.4 Inorganic contaminants in the environment 46, 3.4.1 Assessing contamination status of soils 49, 3.5 Anthropogenic organic chemicals in the soil environment 49, 3.5.2 Chemicals of emerging concern in the environment 53, 3.5.3 Chemical factors affecting organic chemical reactions in soil 54, 3.6 Properties of the elements in soils 55, 3.6.1 Alkali and alkaline earth cations 56, 3.6.6 Major biogeochemical elements carbon, nitrogen, and sulfur 68, 4.2 Thermodynamic approach to aqueous soil chemistry 74, 4.3.1 Example calculation of activity coefficient 82, 4.6 Precipitation and dissolution reactions 88, 4.6.1 Solubility of oxides and hydroxides 89, 4.6.2 Calcite and carbon dioxide in soils 90, 4.6.4 Using equilibrium reactions to model soil mineral precipitation and dissolution reactions 95, 4.8.1 Predicting equilibrium for complexation reactions 99, 4.8.3 Trends in cation ligand affinity 104, 4.8.4 Predicting complexation using the hard and soft acid-base (HASB) concept 105, 4.9 Using software to predict soil solution equilibrium 106, 4.10 Kinetics of chemical reaction in soil solution 107, 5.3 Basic approaches for characterizing soil redox processes 119, 5.3.1 Measuring redox-induced changes in chemical species in soils 119, 5.3.2 Predicting redox processes in soil using redox reactions 121, 5.4.2 Thermodynamic models of redox reactions 123, 5.4.3 Predicting redox reactions using equilibrium constants 124, 5.4.4 Theoretical Eh of redox reactions 126, 5.5 Redox potential limits in natural systems 128, 5.6 The role of protons in redox reactions 129, 5.6.2 Adjusting Eh for pH and species activities 130, 5.7 Prediction of oxidation and reduction reactions in soils 132, 5.7.1 Reduction reactions on the redox ladder 133, 5.7.2 Oxidation reactions on the redox ladder 135, 5.8.1 Other methods to assess redox status of soils 136, 5.9 Soil redoximorphic features and iron reduction in wetlands 136, 5.10 Nitrogen redox reactions in soils 138, 5.11 Important concepts for understanding redox in soils 141, 6 Mineralogy and Weathering Processes in Soils 145, 6.4 Common primary mineral – silicates in soils 157, 6.6 Stability of silicates to weathering 162, 6.7 Chemistry of soil weathering and mineral formation 164, 6.7.1 Initial breakdown of primary minerals 164, 6.7.3 Weathering effects on ion composition in soils 166, 6.8 Formation of secondary minerals in soils 168, 6.8.1 Prediction of secondary mineral formation 170, 6.13 Time sequence of mineral formation in soils 176, 6.14.1 Principles of x-ray diffraction (XRD) for clay mineralogy 181, 7.2 Structural characteristics of phyllosilicates 185, 7.3 Relation of phyllosilicate structure to physical and chemical properties 193, 7.3.4 Cation adsorption and layer charge 195, 7.3.5 Shrink and swell behavior and interlayer collapse 198, 7.4 Detailed properties of phyllosilicates 198, 8 Production and Chemistry of Soil Organic Matter 213, 8.2 Ecosystem carbon storage and fluxes 215, 8.3 Soil organic matter formation factors 217, 8.5 Plant and microbial compounds input into soil 219, 8.9 Function of organic matter in soil 231, 8.9.1 Organic nitrogen, sulfur and phosphorus 233, 8.9.2 SOM influences on chemical processes 233, 8.9.3 SOM influences on physical properties 234, 9 Surface Properties of Soil Colloids 237, 9.3.2 Variable charge on phyllosilicates 240, 9.3.3 pH-dependent charge on Fe and Al oxides 242, 9.4 Point of zero charge of variable charged surfaces 243, 9.6 Hydrophobic regions of soil organic matter 248, 10.1.3 Adsorption of non-charged chemicals to soil particles 254, 10.2.1 Force of ion attraction to charged surfaces 258, 10.2.3 Description of the diffuse double Layer 261, 10.2.4 Interacting diffuse double layers from adjacent particles 265, 10.2.5 Stern modification of the Gouy-Chapman DDL theory 267, 10.3.1 Inner-sphere adsorption on minerals 274, 10.3.3 Inner-sphere metal adsorption on soil organic matter 277, 10.3.4 Inner-sphere metal adsorption in soils 277, 10.4.2 Inner-sphere adsorption of anions 282, 10.5 Adsorption of anthropogenic organic chemicals in soils 286, 10.5.1 Mechanisms of organic chemical retention 287, 10.5.2 Adsorption of charged pesticides 287, 10.5.3 Retention of non-ionic organic chemicals 289, 10.5.4 Predicting organic chemical retention in soil 290, 11 Measuring and Predicting Sorption Processes in Soils 295, 11.3 Predicting sorption using empirical models 297, 11.4 Predicting adsorption using mechanistic models 301, 11.8 Analytical methods for determining adsorption mechanisms 312, 12.3.1 Creation of exchangeable aluminum 319, 12.4.1 Aqueous chemistry of base cations 320, 12.5.1 Organic matter influences on pH 322, 12.5.2 Acidity from the nitrogen cycle 324, 12.5.3 Phosphate and sulfate fertilizer additions to soil acidity 327, 12.5.4 Plant root influences on soil acidity 327, 12.5.5 Protonation and deprotonation of mineral surfaces 327, 12.5.6 Pollution sources of soil acidity 327, 13.2 Distribution and origin of salt-affected soils 333, 13.2.1 Mineral weathering sources of salts 334, 13.2.4 Topographic influence on soil salt concentrations 334, 13.2.5 Human sources of soil salinity 335, 13.3 Characterization of salinity in soil and water 336, 13.3.4 Exchangeable sodium percentage 340, 13.3.6 Other problematic solutes in irrigation water 342, 13.5 Effects of salts on soils and plants 345, 13.6 Salt balance and leaching requirement 346, “Overall, Soil chemistry is a tour de forceof … well, soil chemistry. 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